MEASUREMENT OF CHEMICAL PESTICIDE RESIDUES IN CAPSICUM GROWN IN SOUTH INDIA

Main Article Content

RABIN CHANDRA PARAMANIK
ACHINTO PARAMANIK

Abstract

Capsicum (also known as peppers) is a genus of flowering plants in the nightshade family Solanaceae.Capsicum grown in five districts of Karnataka (Bangalore urban, Bangalore rural, Kolar, Chikkaballapura and Ramanagara) were analyzed for 20 pesticide residues by Gas liquid Chromatography equipped with ECD and FCD. Recovery studies performed at 0.1, 0.5 and 1.0mg kg-1 fortification levels of each compound and recoveries obtained ranged from 743%-97% with relative standard deviation lower than 7.5%. The method showed the good linearity over the range assessed 0.01-1.0mg kg-1 respectively. Capsicum was analyzed for acephate, chlorphyriphos, dichlorvos, phorate, deltamethrin, fenvalerate and cyfluthrin-ȕ residues. Except phorate none of the residues in capsicum crossed the MRL. Phorate was detected in samples from Ramanagara district while 12.5% samples from Bangalore rural, chikkaballapura and Kolar district showed phorate residues exceeding the MRL value of 0.05mg kg-1. Cyfluthrin-ȕ residue is in higher proportion in capsicum samples from Bangalore rural than Bangalore urban. It is therefore required to investigate extensively the monitoring studies covering all the vegetables crops from different agro-climatic zones of Karnataka to know the exact status of pesticide contamination.

Article Details

Section
Articles

References

. Solecki, R., Davies, L., Dellarco, V., Dewhurst, I., van Raaij, M. and Tritscher, A. 2005. Guidance on setting of acute reference dose (ARfD) for pesticides. Food Chem. Toxicol., 43: 1569-1593.

. Berrada, H., Fernández, M., Ruiz, M.J., Molto, J.C., Mañes, J. and Font, G. 2010.

. Surveillance of pesticide residues in fruits from Valencia during twenty months. (2004/5). Food Control, 21: 36-44.

. AOAC. 2000. Official methods of analysis of the association of official analytical chemists. 17th ed. AOAC International, Maryland, USA.

. Anastassiades, M., Lehotay, S.J., Stajnbaher, D. and Schenck, F.J. 2003. Fast and easy multi residue method employing acetonitrile extraction / partitioning and ―dispersive solid phase extraction‖ for the determination of pesticide residues in produce. J. AOAC. Int., 86: 412-431.

. Harry, M. and Pylypiw, J.R. 1993. Rapid gas chromatographic method for the multi-residue screening of fruits and vegetables for organochlorine and organophosphate pesticides. J. AOAC, 76 (6): 1369-1374.

. Michel, A.N. and Steven, J.L. 2003. Fast and easy multiresidue method employing acetonitrile extraction partitioning and "Dispersive solid-phase extraction" for the determination pf pesticide residues in produce. J. AOAC., 86 (2): 412-432.

. Anna, S., Luciana, B. and Mirella, B. 2004. Application of liquid chromatography with electrospray tandem mass spectrometry to the determination of a new generation of pesticides in processed fruits and vegetables. J. Chromatogr. A, 1036: 161 -169.

. Crentsil Kofi Bempah, Jacob Asomaning, Daniel Ayirebi Ansong, Juliana Boateng and Stephen Boahen Asabere. 2012. Contamination levels of selected organochlorine and organophosphorus pesticides in Ghanaian fruits and vegetables.

. Emir. J. Food Agric., 24 (4): 293-301.

. Chen Chen, Yongzhong Qian, Qiong Chen, Chuanjiang Tao, Chuanyong Li and Yun Li. 2011.Evaluation of pesticide residues in fruits and vegetables from Xiamen, China. Food Control, 22: 1114-1120.

. Beena Kumari, Kumar, R., Madan, V.K., Rajvir Singh, Jagdeep Singh and Kathpal, T.S. 2003. Magnitude of pesticidal contamination in winter vegetables from Hisar, Haryana. Environ. Monit. Assess. 87: 311-318.

. Beena Kumari and Kathpal, T.S. 2009. Monitoring of pesticide residues in vegetarian diet. Environ. Monit. Assess. 151: 19-26.

. Beena Kumari, Madan, V.K., Kumar, R. and Kathpal, T.S. 2002. Monitoring of seasonal vegetables for pesticide residues. Environ. Monit. Assess. 74: 263-270.

. Dharinka Stajnbaher and Lucija Zupancic-Kralj. 2003. Multiresidue method for determination of 90 pesticides in fresh fruits and vegetables using solid-phase extraction and gas chromatography-mass spectrometry. J. Chromatogr. A, 1015:185–198.

. Crentsil Kofi Bempah, Archibold Buah-Kwofie, Dzifa Denutsui, Jacob Asomaning and Anita Osei Tutu. 2011. Monitoring of pesticide residues in fruits and vegetables and related Health risk assessment in Kumasi metropolis, Ghana. Res. J. Environ. Earth Sci., 3(6): 761-771.

. Maria, L., Aldana-Madrid, Ana I., Valenzuela-Quintanar, Maria, I., Silveira-Gramont, Guillermo Rodriguez-Olibarria, Patricia Grajeda-Cota, Fabiola G., Zuno-Floriano and Marion G.M. 2011. Residual pyrethroids in fresh horticultural products in Sonora, Mexico. Bull. Environ. Contam. Toxicol. 87: 436-439.

. Ranga Rao, G.V., Sahrawat, K.L., Ch. Srinivasa Rao, Binitha Das, Kirankumar Reddy, K., Bharath, B.S., Rameshwar Rao, V., Murthy, K.V.S. and Wani, S.P. 2009. Insecticide residues in vegetable crops grown in Kothapalli watershed, Andhra Pradesh, India: A case study. Indian J. Dry land Agric. Res. Dev., 24 (2): 21-27.

. Doyeli Sanyal, Anita Rani, Samsul Alam, Seema Gujral and Ruchi Gupta. 2011. Development, validation, and uncertainty measurement of multi-residue analysis of organochlorine and organophosphorus pesticides using pressurized liquid extraction and dispersive-SPE techniques, Environ. Monit. Assess. 182: 97-113.

. Gouri Satpathy, Yogesh Kumar Tyagi and Rajinder Kumar Gupta. 2011. A novel optimized and validated method for analysis of multi-residues of pesticides in fruits and vegetables by microwave- assisted extraction (MAE)-dispersive solid-phase extraction (d-SPE)-retention time locked (RTL)- gas chromatography-mass spectrometry with Deconvolution reporting software (DRS). Food Chemistry, 127: 1300-1308.

. Xingang Liu, Jun Xu, Fengshou Dong, Yuanbo Li, Wenchen Song and Yangquan Zheng. 2011. Residue analysis of four diacylhydrazine insecticides in fruits and vegetables by Quick, Easy, Cheap, Effective, Rugged, And Safe QuEChERS method using ultra-performance liquid chromatography coupled to tandem mass spectrometry. Anal. Bioanal. Chem., 401: 1051-1058.

. Qozowicka, B., Jankowska, M. and Kaczynski, P. 2012. Pesticide residues in brassica vegetables and exposure assessment of consumers. Food Control, 25: 561575.`

. Srivastava A. K., Purushottam Trivedi, Srivastava, M.K., Lohani, M. And Laxman Prasad Srivastava. 2011. Monitoring of pesticide residues in market basket samples of vegetable from Lucknow city, India: QuEChERS method. Environ. Monit. Assess. 176 465-472.